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[3] [5] Topical application also keeps the copper load overwhelmingly local: intact stratum corneum is a substantial barrier to a ~403 Da charged metal complex, which limits systemic copper exposure the same barrier property that limits topical efficacy is what limits topical copper risk

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In practice, the phenolic OH groups in polyphenols act as reducing elements, but at the same time, when the phenoxyl radical is formed, they function as pro-oxidants, which supports from a theoretical point of view the fact that these compounds are activators of the Nrf2 factor, as they interact with the Keap1 protein

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