Metabolism and Bioavailability Metabolism The hydrolysis of glucosinolates, which is catalyzed by a class of enzymes called myrosinases (-thioglucosidases), leads to the formation of breakdown compounds, such as thiocyanates, isothiocyanates, indoles, oxazolidine-2-thiones (e.g., goitrin), epithionitrile, and nitrile (see the article on Cruciferous Vegetables)
However, in a study performed on male mice lacking the gene that encodes for NO synthase 1, these mice were found to have abnormal anxiety levels compared to their counterparts (166, 167)
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doi: 10.3390/biology10050402 15
In hepatocellular carcinoma (HCC) cells, post-translational activation of cystathionine -synthase (CBS) under TNF-induced oxidative stress increases TSS activity through a proteolytically cleaved and highly active form of CBS, increasing cystathionine and GSH production (102), which in turn promotes tumor progression and inhibits ferroptosis
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