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10.3252/pso.eu.ILC2022.2022 92 WalczakR.CaroleB.BenoitN.DescampsE.NathalieD.MegnienS.et al (2018)

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The iodoacetyl group reacts specifically with free sulfhydryl (SH) groupsthe side chains of reduced cysteine residuesvia nucleophilic substitution, in which the thiol displaces the iodide to form a stable, irreversible thioether bond